- Baron Heinrich Zemo's Masters of Evil appear in The Marvel Super Heroes episode "Zemo and his Masters of Evil", consisting of Heinrich, the Black Knight, the Radioactive Man, and the Melter.
- Baron Helmut Zemo's Masters of Evil appear in The Avengers: United They Stand episode "Command Decision", consisting of Helmut, the Absorbing Man, Boomerang, the Cardinal, Dragonfly, Moonstone, Tiger Shark, and Whirlwind.
- Baron Heinrich Zemo's Masters of Evil appear in The Avengers: Earth's Mightiest Heroes, formed by the Enchantress, the Executioner, and Heinrich and consisting of them, Arnim Zola, Wonder Man, the Crimson Dynamo, the Abomination, Chemistro, the Grey Gargoyle, and the Living Laser. They battle the Avengers twice until Heinrich discovers the Enchantress was secretly working with Loki to help him take over Asgard while Thor is away on Earth and betrays her while enacting a plot to use Karnilla's Norn Stones to fuse Earth with Asgard. After the Avengers foil the plot, the Enchantress seeks vengeance on Heinrich and eliminates Chemistro, Living Laser, and Zola, forcing the surviving Masters of Evil to ask for the Avengers' help in stopping her. During the Enchantress' subsequent attack, the Black Panther builds a power dampener, which successfully negates her powers. Wonder Man prevents Heinrich from finishing her off, but when the Enchantress tries to take the last Norn Stone, Wonder Man grabs it simultaneously, causing both of them to disappear. In the aftermath, Heinrich, the Abomination, the Crimson Dynamo, and the Executioner are incarcerated at Prison 42.
- The Masters of Evil appear in Marvel Disk Wars: The Avengers, consisting of MODOK, the Abomination, Baron Heinrich Zemo, Graviton, and Tiger Shark.
- Baron Helmut Zemo's Masters of Evil appear in Avengers: Ultron Revolution, consisting of Helmut, the Beetle, the Fixer, Goliath, Moonstone, and Screaming Mimi. Following failed attacks on Stark Industries and Avengers Tower, the Masters of Evil reappear as the superhero team, the Thunderbolts, via a shrouding device to mask their appearances. However, Screaming Mimi has a change of heart and convinces her teammates to join the Avengers in publicly exposing Helmut, who escapes while the remaining Masters of Evil turn themselves in.
- The Masters of Evil appear in the first season of Marvel Future Avengers, consisting of the Leader, the Enchantress, Ares, the Winter Soldier, and Bruno, a teenage HYDRA operative who underwent genetic manipulation. The group is recruited by Kang the Conqueror and join forces with Hydra and Loki to enact the "Emerald Rain" project, a plan to reverse-engineer Terrigen crystals and use them to mutate Earth's populace to become Kang's new foot soldiers. The Winter Soldier and Bruno later defect, with Bruno joining the Future Avengers.